Hydrochloric acid for pools, also known as muriatic acid, is widely used in pools to lower pH levels, enhance water clarity, and boost chlorine effectiveness. Always refer to guidelines for safe dilution and handling. You can also use this for pool cleaning, acid wash.
Applications:
- Swimming Pool pH Adjustment
- Brick Cleaning & Concrete Etching
- Industrial Processes & Metal Preparation
- Mineral Processing
Guidelines for Brick Cleaning and Etching
- Scrape off excess concrete or mortar and soak bricks with water.
- Prepare a solution by mixing 1 part acid with up to 10 parts water.
- Apply with a brush, wait for the reaction to stop (frothing), then rinse with water.
Hydrochloric Acid for Pools pH Adjustment Instructions
- Add 100 ml of acid per 40,000 litres of pool water to lower pH by 0.1 (e.g., 7.9 to 7.8).
- Run the pool pump for at least 1 hour after adding acid; retest and adjust pH as needed after 8 hours.
*Included in the cost is a $5 deposit for the 20L drum, which is reimbursable upon the return of the empty container.
Technical Reference
Technical Specifications
| Property | Detail |
|---|---|
| Chemical Name | Hydrochloric Acid |
| IUPAC Name | Chlorane (hydrogen chloride in aqueous solution) |
| Common Names | Muriatic acid, spirits of salt, pool acid |
| Molecular Formula | HCl (aq) |
| CAS Number | 7647-01-0 |
| Concentration / Grade | 32% w/w (approximately 10.2 mol/L); technical/commercial grade |
| Physical State | Liquid |
| Appearance | Clear to pale yellow fuming liquid |
| Density | Approximately 1.16 g/mL at 20°C |
| pH (of concentrate) | <1.0 (strongly acidic) |
| Boiling Point | Approximately 84°C (azeotrope at 20.2% w/w); fuming occurs below boiling |
| Solubility in Water | Fully miscible in all proportions |
| Vapour Pressure | Approximately 16 kPa at 20°C (significant fuming at 32%) |
| UN Number | UN 1789 |
| ADG Class | Class 8 — Corrosive Substance; Packing Group II |
| Hazchem Code | 2R |
Applications & Use Cases
- Swimming pool pH reduction: Lowering pool water pH to the recommended range of 7.2–7.6 to optimise chlorine efficacy and bather comfort
- Pool acid washing: Deep cleaning of pool surfaces (plaster, pebblecrete, fibreglass) to remove calcium scale, algae staining, and mineral deposits
- Brick and masonry cleaning: Removal of mortar smears, efflorescence, and calcium carbonate deposits from clay bricks, pavers, and concrete surfaces
- Concrete etching: Surface preparation of concrete slabs prior to application of coatings, sealers, or epoxy floor systems
- Metal preparation and pickling: Removal of mill scale, rust, and oxides from mild steel and iron surfaces prior to galvanising, coating, or welding
- Industrial descaling: Removal of carbonate and silicate scale from heat exchangers, boilers, cooling towers, and process pipework
- Mineral processing: Ore leaching and pH adjustment in hydrometallurgical processes
- Water treatment: pH correction in industrial process water and wastewater neutralisation
- Food processing equipment cleaning: Descaling of stainless steel equipment where food-grade acid is specified (note: food-grade acid required; this technical-grade product is not certified for direct food contact)
- Tile and grout cleaning: Removal of grout haze and calcium-based staining from ceramic and porcelain tiles
Dosing Rates & Guidelines
All dosing rates are indicative based on standard Australian industry practice. Actual rates must be verified by site-specific water testing or surface assessment. Always test and adjust incrementally.
| Application | Dosing Rate / Dilution Ratio | Units / Basis | Notes |
|---|---|---|---|
| Swimming pool pH reduction (residential) | 100 mL per 0.1 pH unit reduction | mL per 40,000 L pool volume | Add in front of the return jets with the pump running. Retest after 4 hours. Target pH 7.2–7.6. Do not exceed 250 mL per dose without retesting. |
| Swimming pool pH reduction (commercial/large) | Proportional to volume; calculate using Henderson-Hasselbalch or pool dosing calculator | mL per 10,000 L | Approximately 25 mL per 10,000 L per 0.1 pH unit. Verify with a calibrated pH meter. Dosing via a chemical dosing pump is recommended for commercial pools. |
| Pool acid wash (full drain) | 1 part acid: 10 parts water | % v/v solution (approx. 2.9% HCl) | Apply evenly to a wetted surface. Allow 30–60 seconds of contact time. Do not allow to dry. Rinse thoroughly. Neutralise runoff with soda ash before disposal. |
| Brick and masonry cleaning | 1 part acid: 10 parts water (general); up to 1:5 for heavy deposits | % v/v solution | Pre-soak brickwork with water. Apply the diluted solution. Allow reaction to cease. Rinse thoroughly. Test on an inconspicuous area first. Avoid sandstock or heritage bricks without specialist advice. |
| Concrete etching (surface preparation) | 1 part acid: 10 parts water | % v/v solution (approx. 2.9% HCl) | Apply to dampened concrete. Allow 3–5 minutes of contact time. Neutralise with bicarbonate of soda solution (50 g/L) and rinse thoroughly with water. Surface should have a fine-sand texture when complete. |
| Metal pickling/rust removal | 5–18% HCl solution (1:1 to 1:5 dilution of 32% stock) | % w/w HCl | Concentration and contact time depend on steel grade and scale thickness. Inhibitors (e.g., hexamethylenetetramine) are typically added in industrial pickling baths to limit base metal attack. |
| Industrial descaling (heat exchangers, pipework) | 5–15% HCl solution | % w/w HCl | Circulate at 40–60°C. Include a corrosion inhibitor appropriate for metallurgy. Neutralise and dispose of spent acid per local trade waste requirements. Engage a specialist contractor for pressurised systems. |
| Cooling tower pH correction | Dosing pump; typically 0.1–0.5 mL/L of blowdown | mL per litre of circulating water | Target conductivity and pH per water treatment programme. Automated dosing with a pH controller is strongly recommended. Interlock with the chemical metering pump. |
| Wastewater/process water pH neutralisation | Titrate to target; typically 0.5–5 mL/L of alkaline waste | mL of 32% HCl per litre of waste | Highly site-specific. Jar test required. Target pH 6.0–8.5 for trade waste discharge per Australian state environmental regulations. |
Dilution Instructions
Critical safety principle: Always add acid to water. Never add water to acid. Adding water to concentrated hydrochloric acid causes violent exothermic spattering and the generation of concentrated HCl fumes, which may result in severe chemical burns and respiratory injury.
- Select appropriate PPE before commencing: Don chemical-resistant gloves (neoprene or PVC, minimum 0.4 mm thickness), chemical splash goggles (not safety glasses), a PVC or rubber apron, and respiratory protection appropriate for the concentration being handled (see Safety & Handling section below).
- Prepare your dilution vessel: Use only chemically compatible containers — high-density polyethylene (HDPE), polypropylene (PP), or PVC. Never use aluminium, zinc, galvanised, or mild steel containers. Ensure the vessel is clean and dry. For large volumes, use a vessel at least twice the final solution volume to allow for safe mixing.
- Measure the required volume of water first: Add the full volume of cold, clean water to the dilution vessel before any acid. For pool pH adjustment, this step is typically omitted — the acid is added directly to the pool water.
- Measure the required volume of acid: Use a graduated HDPE or PP measuring jug dedicated to acid use only. Do not use metal funnels or containers.
- Add acid slowly to water: Carefully pour the measured acid into the water in a slow, controlled stream. Do not splash. Stir gently with a chemically resistant rod (HDPE or glass) during addition. The solution will warm slightly — this is normal.
- Allow to cool before use: Allow the diluted solution to return to ambient temperature before applying, particularly for masonry or surface applications.
- Label the container immediately: Mark the container with the chemical name, concentration, date of preparation, and hazard pictograms in accordance with the Globally Harmonised System (GHS) / Australian Work Health and Safety Regulations.
- For pool pH adjustment (direct addition): With the pool circulation pump running, slowly pour the measured dose of acid directly into the water in front of a return jet inlet. Do not pour near the skimmer box, pool steps, or in shallow areas where bathers may be present. Never pre-mix pool acid in a bucket of pool water — always add acid to the large body of water. Keep bathers out of the pool for a minimum of 30 minutes after dosing and retest pH before re-entry.
Common dilution ratios for 32% HCl stock:
| Target Concentration | Parts Acid (32%) | Parts Water | Typical Use |
|---|---|---|---|
| Approx. 10% HCl | 1 | 2 | Heavy industrial descaling, metal pickling |
| Approx. 6% HCl | 1 | 4 | Moderate masonry cleaning, heavy efflorescence |
| Approx. 3% HCl | 1 | 10 | Standard brick cleaning, concrete etching, and pool acid wash |
| Approx. 1.5% HCl | 1 | 20 | Light cleaning, tile grout haze removal, and sensitive surfaces |
Chemical Compatibility
Compatible materials for storage and handling:
- High-density polyethylene (HDPE)
- Polypropylene (PP)
- PVC (polyvinyl chloride) at ambient temperatures
- PVDF (polyvinylidene fluoride) for pump and valve components
- PTFE (Teflon) for seals and gaskets
- Viton (FKM) elastomers
- Borosilicate glass (laboratory applications)
- Fibre-reinforced plastic (FRP) with vinyl ester resin
Incompatible materials — do not use with hydrochloric acid:
- Metals: Aluminium, zinc, iron, mild steel, galvanised steel, copper, brass — react vigorously with HCl to produce hydrogen gas (flammable) and may cause container or equipment failure
- Stainless steel (304 grade): Susceptible to pitting and chloride-induced stress corrosion cracking; 316L grade offers limited resistance only at low concentrations
- Natural rubber: Degrades rapidly in concentrated HCl; use neoprene or EPDM alternatives
- Polycarbonate and acrylic (Perspex): Chemically attacked by concentrated HCl
Chemically incompatible substances — do not mix with hydrochloric acid:
- Hypochlorites (pool chlorine, sodium hypochlorite, calcium hypochlorite): Reacts to release chlorine gas (Clâ‚‚), a toxic gas with an immediately dangerous to life and health (IDLH) concentration of 10 ppm. This reaction is severely hazardous and has caused fatalities in pool plant rooms. Under no circumstances should acid and chlorine products be mixed or stored in close proximity without adequate segregation.
- Sodium hydroxide / caustic soda/soda ash: Violently exothermic neutralisation reaction; causes spattering if unmixed.




